Please use this identifier to cite or link to this item:
http://dspace.cityu.edu.hk/handle/2031/9406Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Tang, Sik Him (鄧錫謙) | en_US |
| dc.date.accessioned | 2021-04-14T02:33:31Z | - |
| dc.date.available | 2021-04-14T02:33:31Z | - |
| dc.date.issued | 2020 | en_US |
| dc.identifier.citation | Tang, S. H. (2020). Synthesis and mechanistic studies of novel organometallic complex (Outstanding Academic Papers by Students (OAPS), City University of Hong Kong). | en_US |
| dc.identifier.other | chem2020-4036-tsh362 | en_US |
| dc.identifier.uri | http://dspace.cityu.edu.hk/handle/2031/9406 | - |
| dc.description.abstract | In this study, a series of new complexes 1a, 1b and 1c were synthesized produced by using halogen-functionalized alkynes and cis-[Ru(dppm)2Cl2] (dppm = 1,1-bis(diphenylphosphino)methane). Analytically pure crystals were collected for ruthenium N-heterocyclic complexes substituted with fluoride, chloride and bromide. But the yields of Ru-complexes were low in reaction using fluorinated and chlorinated ligands. The complexes were well characterized by NMR spectroscopy and X-ray crystallography. The formations of bi-dentate ligand replacing the two chloride ions via vinylidene pathway followed by R-X-M bond formation and resulted in a complex with distorted octahedral geometry. | en_US |
| dc.rights | This work is protected by copyright. Reproduction or distribution of the work in any format is prohibited without written permission of the copyright owner. | en_US |
| dc.rights | Access is unrestricted. | en_US |
| dc.title | Synthesis and mechanistic studies of novel organometallic complex | en_US |
| dc.contributor.department | Department of Chemistry | en_US |
| dc.description.course | BCH4036 Project | en_US |
| dc.description.programme | Bachelor of Science (Honours) in Chemistry | en_US |
| dc.description.supervisor | Dr. Wong, Alex C. Y. | en_US |
| Appears in Collections: | OAPS - Dept. of Chemistry | |
Files in This Item:
| File | Size | Format | |
|---|---|---|---|
| fulltext.html | 156 B | HTML | View/Open |
Items in Digital CityU Collections are protected by copyright, with all rights reserved, unless otherwise indicated.